Hi Derek,
Have you got sorted yet? (50/50 chance on the TX/RX frequencies.
)
The simplex repeater (MB7IZR) as you may have figured out has the same input and output frequency so set them the same for both. You can do the same for the CTCSS code too.
I believe this connects to the AllStar Digital network but is analogue FM input/output.
(Handy if you don't have DMR facilities.)
On the Duplex repeater (GB3HG) the first frequency is the repeaters transmission so you set that as your RX frequency and then the -0.6Mhz is the offset you programme for your TX so 145.0500MHz.
It can all be a bit confusing when you first start programming repeaters but you will get the hang of it.
The repeater coverage map for GB3HG shows no coverage in your area (your forum profile QTH of Middlesbrough) as shown here :-
https://ukrepeater.net/my_repeater.php?id=821
It may be worth checking out GB3IR as it shows coverage in your area :-
https://ukrepeater.net/my_repeater.php?id=841
(Set your radio TX as 145.1625MHz and RX as 145.7625MHz, CTCSS = 88.5Hz.)
As for the Marine frequencies (I've never done this being about as far away from the sea as you can get) the simplex frequencies mean you should be able to hear both sides ships & shore by setting your receive frequency to the one shown on your list.
For the Duplex these are full duplex so either set your frequency to the 'Shore' frequency to hear them or the 'Ship' frequency to hear the ships. I don't think you can do both on the Anytone but don't shoot me if I'm wrong.
Hopefully that's of use to you.
To check repeaters in your area first find your Maidenhead Locator square here :-
https://www.whatsmylocator.co.uk/
Then simply type in your address to get a locator which will be made up of two letters, two numbers and then a further two letters. (Middlesbrough comes up as IO94jn.)
Then if you go to the RSGB UK repeaters page :-
https://ukrepeater.net/repeaterlist.html?filter=ALL
....you can type in your Maidenhead locator into the 'locator' box and click on the 'calculate' button to bring up a list of repeaters. Then if you click on the '[km]' tab you can see repeaters in your area by distance from you.
A lot of stuff to absorb and apologies for all the links but they may come in useful.
Don't fret if you don't get it right straight away, I think all of us may have struggled to get our head around repeaters to start with but before long you'll become an expert at it.
Have fun and all the best,
Victor